Return to Presentation Details

Kinetic Molecular Theory of Gases

9th and 10th Grade Informational Reading Texts

Gases were among the first substances studied using the modern scientific method, which was developed in the 1600s. It did not take long to recognize that gases all shared certain physical behaviors, suggesting that gases could be described by one all-encompassing theory. The kinetic molecular theory of gases is a model that helps us understand the physical properties of gases at the molecular level.
It is based on the following concepts:
1. Gases consist of particles (molecules or atoms) that are in constant random motion.
2. Gas particles are constantly colliding with each other and the walls of their container. These collisions are elastic; that is, there is no net loss of energy from the collisions.
3. Gas particles are small and the total volume occupied by gas molecules is negligible relative to the total volume of their container.
4. There are no interactive forces (i.e., attraction or repulsion) between the particles of a gas.
5. The average kinetic energy of gas particles is proportional to the absolute temperature of the gas, and all gases at the same temperature have the same average kinetic energy.
The kinetic molecular theory of gases describes this state of matter as composed of tiny particles in constant motion with a lot of distance between the particles. Because most of the volume occupied by a gas is empty space, gas has a low density and can expand or contract under the appropriate influence. The fact that gas particles are in constant motion means that two or more gases will always mix as the particles from the individual gases move and collide with each other. The number of collisions the gas particles make with the walls of their container and the force with which they collide determine the magnitude of the gas pressure.
Gas particles are in constant motion, and any object in motion has kinetic energy (Ek). Kinetic energy, for an individual atom, can be calculated by the following equation where m is the mass, and u is the speed: Ek = 1/2 mu2
Overall the molecules in a sample of gas share average kinetic energy; however, individual molecules exhibit a distribution of kinetic energies because of having a distribution of speeds. This distribution of speeds arises from the collisions that occur between molecules in the gas phase. Although these collisions are elastic (there is no net loss of energy), the individual speeds of each molecule involved in the collision may change. For example, in the collision of two molecules, one molecule may be deflected at a slightly higher speed and the other at a slightly slower speed, but the average kinetic energy does not change.
According to the kinetic molecular theory, the average kinetic energy of gas particles is proportional to the absolute temperature of the gas.